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Are the machines networked? Do you have a portable hard drive? How clued up are you on pulling the HD out of one machine and hooking it up in the other?
failing that.. get yourself a memory stick... put them onto that from your old pc and then transfer them to your new one!
depends on how many itunes you have and the size of the memory stick.. might take you a few runs back and forth between machines!
my 15 year old is good at transferring hard drives!